By Rui Shang
This thesis offers the newest advancements in new catalytic C–C bond formation equipment utilizing simply obtainable carboxylate salts via catalytic decarboxylation with solid atom economic system, and applying the sustainable point iron because the catalyst to without delay turn on C–H bonds with excessive step potency. during this regard, it explores a mechanistic figuring out of the newly stumbled on decarboxylative couplings and the catalytic reactivity of the iron catalyst with the aid of density sensible thought calculation.
The thesis is split into components, the 1st of which makes a speciality of the improvement of a sequence of formerly unexplored, reasonably cheap carboxylate salts as priceless construction blocks for the formation of assorted C–C bonds to entry important chemical compounds. In flip, the second one half is dedicated to numerous new C–C bond formation methodologies utilizing the main ubiquitous transition steel, iron, as a catalyst, and utilizing the ever present C–H bond because the coupling partner.
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