By W. A. E. McBryde
This monograph contains values made up our minds in non-aqueous or combined solvents, in addition to these for quite a few ""mixed"" steel complexes incorporating those bases and a moment ligand. The survey additionally includes identified values for the enthalpies and entropies of formation for the proton- and metal-ion complexes. The compilation exhibits the stipulations less than which the equilibrium constants follow and the tools through which they have been decided. The acid-base homes of the compounds are represented via the acidity consistent of the phenanthrolinium or bipyridinium ion expressed as a pK price. approximately all of the values indexed have been got both potentiometrically or spectrophotometrically, either one of which rely essentially on measurements of pH or hydrogen-ion focus.
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Additional info for A Critical Review of Equilibrium Data for Proton- and Metal Complexes of 1,10-Phenanthroline, 2,2'-Bipyridyl and Related Compounds: Critical Evaluation ... Metal Complexes Pt. A (IUPAC Publications)